MFI in polymers: What it is and why it is key in processing

The Melt Flow Index (MFI), also known as the Melt Flow Rate (MFR), is a key parameter in the thermoplastics industry. It measures the amount of molten material that flows through a die over a period of 10 minutes. Expressed in grams per 10 minutes (g/10 min), MFI is determined under specific temperature and load conditions. This parameter is essential for assessing a polymer’s processability and predicting its performance in different manufacturing techniques.
Why is MFI important in polymer processing?
MFI in polymers provides insights into a polymer’s viscosity and molecular weight, making it a crucial factor when selecting materials for various applications:
- Injection Molding: Polymers with high MFI flow more easily, improving mold filling and enabling the production of detailed, precise parts at higher production rates.
- Extrusion & Blow Molding: Low MFI materials offer better shape retention, which is essential for producing high-quality, defect-free products.
- 3D Printing: The right MFI ensures consistent extrusion and high-quality prints.
A high MFI typically indicates lower molecular weight and lower viscosity, making the polymer flow more easily. Conversely, a low MFI suggests higher molecular weight, which is generally associated with better mechanical properties, such as higher impact and tensile strength.
How is the Melt Flow Index (MFI) measured?
MFI testing follows standardized methods like ASTM D1238 or UNE-EN ISO 1133. The procedure involves:
- Sample preparation: The polymer sample is weighed and placed into a preheated barrel.
- Heating: The sample melts at a specific temperature depending on the material (e.g., 190°C for polyethylene). A piston is placed on top to compact it.
- Load application: A defined weight is applied to the piston, pushing the molten polymer through a capillary die at constant pressure.
- Measurement: The extruded material is collected, the time is recorded, and the sample is weighed to calculate the MFI.
How to modify the Melt Flow Index? (Use of flow modifiers)
In plastic recycling and processing, materials with different MFI values are often mixed, creating challenges in optimizing material performance. Flow modifiers help adjust the MFI—increasing or decreasing it without compromising the polymer’s properties—ensuring compatibility with specific processing needs.
For example, avanMFI PLUS 2 PO, developed by Avanzare, increases MFI in all types of polyolefins. Adding 3% of this modifier to HDPE can raise its MFI from 11 g/10 min to 24 g/10 min, while a 5% addition increases it to 31 g/10 min.
Benefits of using flow modifiers:
- Enhances processability in injection molding and extrusion.
- Improves polymer blend compatibility.
- Reduces costs by optimizing material performance.
The Melt Flow Index (MFI) is a critical parameter in polymer manufacturing, directly affecting processing efficiency and final product quality. Understanding and adjusting MFI with advanced additives, such as flow modifiers, enhances material performance, making it an essential factor for manufacturers and engineers.
Below, you can see a video of avanMFI PLUS 2 PO in action!